Some Nuclear Reactors use liquid sodium metal to transfer heat from the reactor chamber to the steam turbines. So It must have some great heat tranfer or sinking ability but I would'nt worry about using liquid sodium. Its explosive on contact with air and it smells fatal.
regards
sbdwag
I don't know this for certain, but I've been
told that liquid sodium is actually the best
elemental electrical conductor there is, higher than silver, gold, any of those elements. That electrical conductivity would give it a very high thermal conductivity, as well.
The other advantage of a liquid though, is of course the ability to circulate it, so you get convection along with conduction for heat transfer.
I have to
thank you for this AWESOME explanation you gave me
Thanks man! I can't believe I just came from taking a "Material Science" exam 5 hours ago at college and I didn't know this (though we've only studied metals so far).
Excellent analogies
However, I don't understand how heat is generated by phonons. Are the vibrations transformed into heat because of the vibration of ions? (are diamonds ionized?). I mean, how is heat transferred from one end to the other if electrons aren't free, do ions crash with each other and transfer energy?
Heat is not generated by phonons, heat is
transferred by phonons. The heat is already there on the hot end. The simplest case is a rod that has a hot end and a cold end (let's say a rod of something like diamond, no free electrons, but good phonon transport). On the hot end, the atoms have higher average kinetic energy. That kinetic energy is in the form of a vibration, each atom is vibrating with some energy, and the average vibrational energy is the temperature. For reference and to give you the scale here, an average energy of 1 eV gives you a temperature of ~11,605K. So yeah, 1 atom at 100C/373K has a VERY low vibrational energy, and this makes perfect sense, since you have so many atoms. It's not a big vibration, it's tiny.
The higher the "temperature" (in quotations because I like to think of temperature as an average, and an average has little meaning when talking about one atom) of an individual atom, the more it's vibrating. The fact that the atom is bonded to another atom means the bonded atom will ALSO start vibrating, due to the first one vibrating. If one atom moves left, the one next to it is pulled left. The first one moves back right, the other is pulled back right. The bonds we're talking about are pretty much always some form of a Coulombic attraction, so it's the electrical attraction/repulsion making each atom affect its neighbors as it displaces. an atom displaces, which displaces its neighbors because atoms always want to be at some set equilibrium distance from one-another. That is carried out over and over, as that vibration is transferred to every adjacent atom all the way down the line. The energy of the hot side is in the form of the atom vibrations on that side, and through phonons, you end up with atoms vibrating on both sides, the hot and cold side equalize to the same temperature, as those propagating vibrations transfer that kinetic energy from high-energy atoms to low-energy atoms.
Atoms don't necessarily "crash" into one another, but every atom it always vibrating around some average position. Since each atom has a bond with its nearest neighbors, one atom vibrating will affect all the adjacent atoms, over and over again through the whole crystal. This process is very efficient in diamond because the bonds themselves are so strong: instead of a loose spring like in a metal, the spring between carbon atoms in diamond would be a very stiff spring, almost a solid bar of a connection. Think about a very loose spring between 2 balls: moving one ball doesn't move the other very much, because the spring is so "un-stiff". But you put a very stiff spring, or even a stick, between the two, and you get one atom being very heavily influenced by the vibration of the other. So diamond transports its phonons much more efficiently, with its stiffer bonds.
The energy "comes from" whatever your heat source is, but then is transferred from hot to cold through phonons or electrons. Well, those are the main 2 transfer mechanisms in solids. You can also sometimes get ions to carry heat if you have free ions in the solid, or you can even transfer heat within a solid through radiation under the right circumstances.
As far as if the carbon atoms in diamond are "ionized", that's not really what is in play with phonon transport, phonon transport is the physical interaction of neighboring bodies that interact Coulombically as they vibrate. Are the atoms ionized? Not really, the carbon atoms are in hybrid orbitals (sp3 I think?), so each atom is not technically in the "ground state" that would exist if a carbon atom were isolated all by itself, but I think of ionized as having an electron removed entirely from the atom such that it is no longer localized, which doesn't happen in pure diamond. All the atoms are still localized to their bonds in pure diamond/carbon, and the solid as a whole is in a ground state, seeing as how it is extremely stable and definitely in a low-energy state.