You should probably look into combining 445nm and red if you want to make magenta. 405nm is hard to see, more expensive per mW, the diodes can only go up to about 500-600mW, and the diodes are a lot more sensitive to shocks, etc.
The CIE diagram you see is also normalized for brightness. So if you were combining beams of equal brightness, you'd get those colors, but not equal
power. The reality is that your eyes are more sensitive to some wavelengths of light than others and you need more power for some wavelengths to make them seem as bright as others. You can look at your eye's general sensitivity to certain wavelengths
here. For example, 1W of 638nm red is roughly as bright as 200mW of 532nm green and 6W of 445nm blue. Those ratios aren't exact, as those are daylight conditions, but people use R:G:B ratios such as 2:1:4 depending on lighting conditions.