Krazer:
It of course depends on your application, but for an application where you are taking a collimated beam and focusing it to a spot (as would be used for a telescope or diode collimator), a bestform will outperform a plano-convex which will outperform a bi-convex. You can do better with a doublet (such as an achromatic lens),
and for monochromatic light you can always do the best with an aspheric lens.
The difference between a bestform or achromat or ashpere has to do with the level of optimization applied to the lens design. When designing a plano-convex lens your only degree of freedom (for a given focal length and optical material) is the lens thickness, and for almost all applications it works out that the thinnest possible lens will perform best. When designing a bestform lens the lens maker has 3 main degrees of freedom, the curvature of input/output faces and the lens thickness. When designing an achromat you have even more degrees of freedom, there are the input/output curvatures of each optical element, the thickness of each optical element, the spacing between them, and the material they are each made of, which allows the lens maker even more freedom. With an ashpere the lensmaker is no longer constrained to using spherical surfaces, so there is a virtually infinite number of degrees of freedom (a typical asphere will have about 10 coefficients that determine the shape of the surfaces).
You can try playing with OSLO (a limited edition is free for students)
http://www.lambdares.com/oslo-university-program which will directly give you plots of the lens performance for different optical designs.