Both LPF and Google are your friend:
https://www.rp-photonics.com/vanadate_lasers.html
Vanadate crystals are naturally
birefringent, which eliminates thermally induced
depolarization loss in
high-power lasers. Also, the laser
gain is strongly polarization dependent (→
polarization of light); the highest gain is usually achieved for polarization along the
c axis. The
pump absorption is also strongly polarization-dependent (except at special wavelengths), which can cause problems e.g. when using a
fiber-coupled pump source with drifting polarization.
Nd:YVO4 lasers are usually
diode-pumped, but can also be
lamp-pumped. Compared with Nd:YAG (→
YAG lasers), Nd:YVO4 exhibits a much higher
pump absorption and
gain (due to the very high absorption and laser
cross sections), a broader
gain bandwidth (around 1 nm), a much broader wavelength range for pumping (often eliminating the need to stabilize the pump wavelength), a shorter
upper-state lifetime (≈ 100 μs for not too high neodymium
concentrations), a higher
refractive index, a lower thermal conductivity, and birefringence. The consequences of these differences for various
modes of laser operation are the following:
- For continuous-wave operation, Nd:YVO4 allows overall similar performance to Nd:YAG in cases with medium or high power. Whereas the thermal conductivity is worse, the temperature coefficient of the refractive index is smaller, so that thermal lensing is not stronger. Due to its high gain efficiency, Nd:YVO4 is better than Nd:YAG for lasers with very low threshold pump power.
- Nd:YVO4 is extremely well suited for passively mode-locked lasers with very high pulse repetition rate; nearly 160 GHz have been demonstrated. This feature results mainly from the high laser cross sections and the strong pump absorption.
- For Q-switched lasers, Nd:YVO4 does not allow for pulse energies as high as for Nd:YAG, because its capability for energy storage is lower than that of Nd:YAG due to the lower upper-state lifetime and the high gain efficiency. On the other hand, Nd:YVO4 is better suited for high pulse repetition rates, where it still allows the generation of fairly short Q-switched pulses.
Compared with Nd:YVO4, Nd:GdVO4 has a similar thermal conductivity, a slightly shorter emission wavelength (1063 nm), a somewhat larger
gain bandwidth, lower emission
cross sections, and still higher pump absorption. Note, however, that the published data concerning thermal conductivity of vanadate crystals differ considerably, so there are some significant uncertainties.
Pay no attention to the man behind the curtain.... This place ought to be renamed Laser Oz.