1)The flow rates I mentioned are based on the readout from a flowmeter calibrated for the kind of gas that we're monitoring.
I trust your flow rate measurement
I was simply commenting that my guesstimate of a 7m/s flow speed was too small!
2) The goal is to only have one sample per particle (the precision is not complete because if two small particles are passing through the beam at the same time, it should show up as a particle twice its size) and we are, for the most part, accomplishing that.
I suspect that you are easily accomplishing that! It appears your sample period is 8 microseconds and the events you are counting happen in nanoseconds.
3) The reaction of the PMT to light is as close to immediate as electrons can be.
The Photomultiplier recieves a photon and produces a current. There is a finite amount of time between receiving a photon and the photocurrent reaching its peak value --- this is the devices rise time. A quick google search suggests that rise times of PMTs may on the order of a few nanoseconds. Because it takes something on the order of 1 nanosecond to produce the current signal, the bandwidth of the device is something on the order of 1 GHz. The actual bandwidth of your device is probably not too far from this.
4) As you can see in the pictures I posted (all of which are without particles), the initial onset of the particles are simply spikes which seem to evolve into the square
waves that are shown in the other image. All particles show up as a single spike with an amplitude proportional to the particle size.
You must have an integrating ADC then.
5) It is a very high speed DAQ device (up to 50k samples/second), but I do not have a true oscilliscope available. With a true O-scope, I would not have the datalogging capability that I have with the sbRIO board. The impulses also happen so fast, I would have a hard time distingushing them in the signal. This way I can gather the data, and analize it in real time in an effort to isolate the problem.
The DAQ you are you using is quite nice, as far as DAQs are concerned. However, DAQs are relatively poor in temporal resolution as compared to the average oscilloscope (DAQs usually emphasize multi-channel and high resolution, whereas oscilloscopes usually emphasize high bandwidth). I understand that you want to capture aerosol particle events as a single sample spike; however, that means you are not resolving the full bandwidth of analog signal from the PMT... for the purposes of your counting device, you don't have to resolve the full bandwidth. This is not the issue.
The problem is understanding what the noise signal is. It is unclear from the time traces you have supplied whether your DAQ device is capturing the full bandwidth of this rouge signal. If this noise signal is composed only of frequency content at 25kHz and lower, then your DAQ measurement is sufficient to characterize the noise signal; however, it does not appear that the time trace of the noise signal is temporally resolved.
Resolving the frequencies is helpful for determining the source of the noise. Many switching-type circuits have switching frequencies in the 100s of kHz. Many op-amp circuits may "ring" at MHz. Because it's intermittent, I suspect that there is some device which is turning on and causing these bouts of noise in your signal. That device may be located inside or outside your device. The character of the noise may help you determine the culprit
What environment is this device being used in? What other machines are in the lab? You mentioned a compressor. Are there process chillers, computers, monitors, fans, power supplies, lasers? Mechanical vibrations?
Is there a possibility of retro-reflection of laser energy back into the diode?
You say the problem gets better after switching out diodes.. why kind of alignment process do you do when switching diodes?