kenrok1 said:
So based on the Luminous Efficacy table would a 405nm laser more visible in complete darkness, since the 405nm does not cross into the phototopic range (assuming it no competition from phototopic light sources)?
"More visible" implies a comparison with something else. Yes, by itself a 405nm beam will be visible in complete darkness, especially if the eyes have dark-adapted, but will be less visible than a 473nm beam due to the much increased luminous efficiency at this wavelength. If there is not enough energy to stimulate photopic vision, both beams will appear to be a shade of gray.
However, there is another factor which comes into play; atmospheric scattering can increase the
apparent luminous efficiency at short wavelengths. The atmosphere scatters 400nm light over nine times as much as 700nm light, so as you go shorter in wavelength, you get more scattered light, which is what makes the beam visible in the first place (if the luminous efficiency were the
same at all wavelengths, beam visibility would still increase at shorter wavelengths).
http://hyperphysics.phy-astr.gsu.edu/hbase/atmos/blusky.html#c2
So there are several factors that determine just how visible "X color" beam will be how visible under "Y conditions".
The tremendous luminous efficiency of 507nm light (blue-green, turquoise) can be appreciated by lighting up a blue-green LED outside at night after the eyes have had time to fully adapt. It lights up the surroundings for a surprising distance, yet there is no
color except close by, where there is enough light to engage photopic vision also. On the other hand, a red LED only lights the immediate vicinity.