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Keep a bottle of strawberry syrup around and you got yourself a never ending sno-cone..
You shouldn't need to be too precise.. What you do is tune the TEC over a period of time that allows the diode to warm up to where you want it. Once you got the TEC tuned to this maximum temperature, it should stay that way. It will take the system a little bit to get to this point, but all lab lasers have a published warm-up time. Yours would be no different than that.
I guarantee you you've licked ice before.. unless you've never had a popsicle.
Oh, Okey... I get it now... but wouldn't be better to hav it for example at around 0 Celsius?