Thorium and refined DU plate has always been on my wishlist.
I have a small 1/4gram sample of U238 but it is just drilling scraps. I have some pitchblende that I keep in a lead cask in the basement (overkill) that is considerably hot, somewhere around 15mR/hr. I had a 35mR/hr piece of autunite but sold it a few years back.
I keep my sealed RAD samples on my office desk as conversation pieces; vaseline (uranium) glass shot-glasses, U238 sample in ampoule, and a Tritium + phosphor ampoule. In my office I even keep a sealed Ra-226 Vacuum tube (only 8mR/hr on contact, mostly gamma), but not at my desk as it takes about 3ft for the gamma levels to die off sufficiently.
The biggest issue with ore and rock based samples is the radon emissions. The actual radiation is easy to shield and contain (space works best, but high Z materials too of course), it is the radon and radon daughters that become a problem whenever quantity of ore increases. Large collections should be forced air ventilated to the outside or stored outside.